Molecular lasers have a wide variety of uses, ranging from materials processing to medical applications. These high-power lasers generally produce gain over a wide spectral range. Gratings are used in these lasers to control and narrow the lasing wavelength.
Molecular lasers, operating both pulsed and continuous-wave (cw) in the infrared, typically have their output wavelength tuned by Littrow-mounted gratings. High efficiency is obtained by operating in the first order at diffraction angles >20°. This corresponds to l/d ratios from 0.67 to 1.8 (where d is the groove spacing), which ensures that only the zero and first orders can diffract. The output will be polarized in the S-plane (i.e., with the electric vector perpendicular to the grooves) because the efficiency will be several times greater than in the P-plane (electric vector parallel to the grooves).
Dispersion is a function of the tangent of the diffraction angle b and is chosen from medium (b ≈ 20°) to very high (b > 50°) as required. Note from the master grating options below, which summarizes gratings most suitable for molecular laser tuning, that high efficiency corresponds to diffraction angles that can be significantly greater than the groove or blaze angles. This is a consequence of the electromagnetic nature of diffraction from deep groove gratings. For maximum efficiency, any of these gratings can be supplied in the form of gold replicas.
Some molecular lasers operate at high power, capable of destroying gratings. In the case of pulsed lasers, extra thick replica films may be of help. In the case of cw lasers, replicas on metal substrates are superior to glass because of greater thermal conductivity; in some cases it is advisable to use water cooled substrates. In all cases, close attention to groove geometry maximizes reflection, minimizes absorption, and leads to improved grating performance. The informati0on below serves as a guide to the typical power levels a grating can be expected to survive.
- Pulsed lasers at 1.06 μm
- Standard gold replica gratings can withstand 300 mJ/cm2 pulses of 100 ps duration.
- CW lasers at 10 μm
- Standard gold replica on copper 100 W/cm2
- Water-cooled gold replica on copper 200 W/cm2
There are a number of masters available which are used to produce replicas with high S-plane efficiency for use with CO2, CO, HF, or DF lasers (see below). For this type of application, we suggest you advise us of the following specifications:
- Spectral region of interest
- Peak power
- Pulse duration
- Beam size
The gratings below are suitable for use in the specific molecular lasers indicated. Gratings in this table are listed by laser type. The maximum ruled area is groove length x ruled width. Click on a Master Grating Code (last 4 digits of a grating's part number) below to view master grating efficiency curves. Use the request a quote to get a quote based on your requirements.