The peak efficiency of a blazed (triangular-groove) transmission grating occurs when the refraction of the incident beam though the mini-prism that constitutes a groove lies in the same direction as the diffraction given by the grating equation. Unlike reflection gratings, the groove angle is much larger than the blaze angle for a transmission grating, since the phase retardation doubles upon reflection but is multiplied by n-1 for a transmission grating, where n is the refractive index of the grating medium.
Applying Snell's law to the interface between the groove facet and air,
n sinχ = sin(χ+β)
Combining this relation with the grating equation, yields the relationship between the blaze angle βB and the groove angle χ:
tanχ = sinββ / (n - cosββ)
For small groove angles and for λ << d, a useful approximation to Eq. (3) relates the blaze wavelength of a reflection grating to that of the corresponding transmission grating. For transmission gratings used in air or vacuum, the ratio of its blaze wavelength (for normal incidence) to that of the equivalent reflection grating (used in Littrow) is
λβ (trans) / λβ (ref) ≈ (n - 1) / 2
where is the blaze wavelength of the corresponding reflection grating. This approximate formula, rarely in error by more than ten percent, simplifies conversion of information in the Grating Catalog from reflection gratings to transmission gratings. Taking n ≈ 1.6, which is true for most transmission gratings, yields
λβ (trans) / λβ (ref) ≈ 0.3
A corollary to this approximation is that, for n ≈ 1.6, the grooves of a transmission grating are about 10/3 times as deep as those of the corresponding reflection grating. For small diffraction angles (i.e., diffraction near the normal), this ratio holds for the angle χ as well.
The choice of groove angle for transmission gratings is limited by total internal reflection effects:
χ ≤ arcsin (1/n)
For n ≈ 1.6, this yields about 40° as the upper limit on χ, though in many cases the effective limit is somewhat lower. This means that transmission gratings cannot be used for high-dispersion applications.