namely, the blaze wavelength in order m (Littrow configuration) is approximately equal to the blaze wavelength in the first order, divided by m. For holographic gratings (whose grooves are sinusoidal), Eq. (4) is not valid [see Loewen et al.]
The Littrow blaze angle θB is defined as the diffraction angle (in the Littrow condition) for the blaze wavelength:
mλB = 2dsinθB (5)
When moving off the Littrow condition (i.e., when α ≠ b ), the blaze wavelength and blaze angle generally satisfy the condition
mλB = 2dsinθBcos(α - θB) (6)
That is, the blaze wavelength decreases with the cosine of the angle between the incidence angle α and the Littrow blaze angle θB. Eq. (6) may be very accurate or an approximation at best, depending on the groove profile and illumination conditions.
While it is relatively straightforward, as shown above, to determine the wavelength λB of maximum efficiency, it is more difficult to determine the maximum efficiency itself. Since this calculation requires the use of Maxwell's equations, it is generally addressed by computer simulation. There are a handful of computer-based grating efficiency programs, some of which are available commercially; Richardson Gratings uses PC Grate to simulate the efficiency behavior of its gratings.