Certain organic dye molecules can act as radiating species for lasing since they have sufficiently long lifetimes in their upper energy levels and can therefore radiate energy from that level instead of losing energy due to collisions. To ensure the proper concentration of radiating species are present, the dye molecules (typically in powder form) are dissolved in a solvent at a concentration of about one part in ten thousand. Due to this solution form, the system is known as a liquid dye laser. Dye lasers are optically pumped by either flashlamps or other lasers. Each dye molecule, due to its overlapping electronic/rotational/vibrational transitions, has a wide homogeneously broadened gain spectrum on the order of 30-50 nm. By utilizing many different dye molecules, the laser can be tuned over a wide spectrum in the UV, VIS, and near-infrared (NIR) (see Figure 2). Combining this broad gain bandwidth with a frequency-selective element allows wide tunability coupled with a narrow spectral bandwidth. As a result, the dye laser has traditionally been used for various spectroscopic applications. Dye lasers require significant maintenance due to the decomposition of the dye when dissolved in its solvent. Therefore, DPSS lasers coupled with nonlinear frequency conversion (see Spectral Tunability) have largely replaced dye lasers in many applications.
A semiconductor laser is often referred to as a laser diode since it operates like a diode with current flowing in the forward direction of the junction. By injecting charge carriers into the region of space defined by the junction, recombination radiation can occur. Provided this current injection is strong enough, a population inversion can be achieved and stimulated emission will occur. Due to the large refractive index difference between the semiconductor material and air, the semiconductor crystal surface can possess sufficient reflectivity to act as its own resonator cavity. These two characteristics, electrical pumping and compact laser design, coupled with the maturity of the semiconductor manufacturing process, has enabled laser diodes to gain a number of advantages over other types of lasers, including high power and efficiency, small size, as well as compatibility with electronic components. Unsurprisingly, they are one of the most important classes of lasers in use today, not only because of their use in applications such as optical data storage and optical fiber communication, but also because they serve as pumping sources for solid-state lasers.
The term solid-state laser refers to a laser whose gain medium consists of active ion species introduced as impurities in an optically transparent host material (typically crystals or glasses). As detailed in Light-Matter Interactions in Lasers and Required Components for Lasing, materials for laser operation should possess strong and spectrally-narrow transition cross-sections, strong absorption bands for pumping, and a long-lived metastable state. Ions that have optical transitions between states of inner, incomplete electron shells generally exhibit these characteristics. However, these ions must be protected or shielded from other ions to prevent loss of these desired characteristics. This is accomplished by incorporating the ions in a solid host material whose lattice allows for ion doping levels sufficient for a gain medium while simultaneously shielding the ions from one another. According to Required Components for Lasing, solid-state lasers achieve their population inversion through optical pumping, which can be accomplished by using a flashlamp or direct pumping from another laser source such as a laser diode or a DPSS system.
Formula |
Name |
Crystals |
Y3AI5O12 |
Yttrium Aluminum Garnet, YAG |
Gd3Ga5O12 |
Gadolinium Gallium Garnet, GGG |
AI2O3 |
Sapphire |
LiSrAIF6 |
LiSrAIF6 |
Mg2SiO4 |
Fosterite |
YLiF4 |
Yttrium Lithium Fluoride or YLF |
YVO4 |
Yttrium Vanadate, YVO |
Glasses |
Silicate-based |
e.g. Si02 or fused silica |
Phosphate-based |
|
Table 2: Table showing formulae and common names of various crystal and glass solid-state host media.
The host material for a solid-state gain medium must possess both unique microscopic lattice properties and appropriate macroscopic mechanical, thermal, and optical properties. These host materials can be organic matter, ceramics, crystals, and glasses but generally fall into the latter two categories. The most common crystal and glass solid-state host materials are given in Table 2. Crystal hosts have several benefits, including narrower laser linewidths, lower laser thresholds which allow for lower doping levels, and higher thermal conductivities. Compared to crystals, glass hosts have many distinct merits: they have lower melting temperatures and can therefore be fabricated at a lower cost and in larger dimensions, they possess high optical quality, and can be doped homogeneously at higher concentrations. However, they have much lower thermal conductivity than crystals and therefore are utilized mainly for systems that operate at high peak powers and low repetition rate. Line-broadening behavior in solid-state lasers is typically dictated by the host medium with crystalline hosts generating homogeneous broadening and glass hosts giving inhomogeneous broadening.
The majority of dopant ions used in solid-state laser media are transition-metal and lanthanide-metal (or rare-earth) ions. The most common transition-metals used are titanium (Ti) and chromium (Cr) while the lanthanides are neodymium (Nd), ytterbium (Yb), erbium (Er), thulium (Tm), and holmium (Ho). The dopant ions are generally dispersed throughout the host with a concentration (typically around one part in one hundred) depending on the dopant, host material, and application. These ions possess electrons that are surrounded by a “screen” (of electrons from the host material) that protect these electrons from interacting with neighboring dopant ions. Therefore, the ions can radiate their energy rather than decay by collisions similar to the way that organic dye molecules behave when in a liquid solvent. When these ions absorb light, the energy ends up in an excited energy level that serves as the upper laser level. By virtue of the screening provided by the host material, this upper level has a very long lifetime (the metastable level) before it radiatively decays. A population inversion can occur (see Figure 1) because the lower laser levels are being rapidly depopulated by collisions with the neighboring atoms as these levels are not protected the way the upper levels are.