Selecting the proper mirror for an application requires consideration of a number of factors, including reflectivity, laser damage resistance, coating durability, thermal expansion of the substrate, wavefront distortion, scattered light, and cost. These mirror characteristics depend on the optical coating, the substrate, and the surface quality. The optical coating is the most critical component of a mirror as it dictates its reflectivity and durability. Processes for depositing high-quality optical coatings are discussed in
Optical Coatings. Optical mirror coatings are typically made up of either metallic or dielectric materials. A common situation for mirror applications is when light is incident from air (
n1 = 1) onto the optical coating material and so the reflectivity given by Equation (1) is dictated solely by the material’s index of refraction (
n2). By virtue of their conductivity, metals have a complex index of refraction with a large imaginary part over a very wide wavelength range. This gives rise to a large reflectivity that is relatively insensitive to wavelength, which gives metallic mirrors their shiny appearance. Metallic coatings are usually made of silver, gold, or aluminum and the resulting mirrors can be used over a very broad spectral range (see Figure 3). Metallic coatings are relatively soft, making them susceptible to damage, and special care must be taken when cleaning. Mirrors with dielectric coatings are more durable, easier to clean, and more resistant to laser damage. However, as a consequence of their dispersive and predominantly real indices of refraction, dielectric mirrors have a narrower spectral reflectivity and are typically used in the VIS and NIR spectral region. There is greater flexibility in the design of dielectric coatings compared to metallic coatings (see
Optical Coatings). When compared with metallic mirrors, a dielectric mirror can offer higher reflectivity over certain spectral ranges and can offer a tailored spectral response (see Figure 3).