The smaller diameter, less expensive spheres necessarily have smaller utility ports and very high throughput. In fact, the throughput may be so high, depending on the light source, that filters or fiber optic cables are required to prevent detector saturation. The port fraction of the smaller spheres, however, is very high. Consequently, the measurement data generated from a small integrating sphere will be less accurate than the same application using a large sphere.
The larger integrating sphere exhibits less throughput than the smaller spheres and high optical attenuation, thereby introducing a higher signal-to-noise ratio. These spheres are more flexible but, at the same time, are more expensive to manufacture.
The cost effective barium sulfate coated GPS integrating spheres are constructed of two aluminum hemispheres. The hemispheres are joined by an anodized flange cover with screws. The effective spectral range of barium sulfate is 350 - 2400 nm, although the hemispherical reflectance falls off slightly above 1850 nm. This type of sphere is adequate for most radiation measurement applications in the visible and NIR spectrums.
Diffuse gold coating is an electrochemically plated, diffuse gold-metallic coating that exhibits high reflectance over the near-infrared and infrared wavelength regions from 0.7 to 20 ?m. The gold spheres are constructed in the same manner as the barium sulfate spheres, except that the external flat surface and port frames are gold-plated as well. A gold GPS is well-suited for infrared laser applications. Whereas a barium sulfate coating may lose its reflectance at high temperatures, the diffuse gold remains stable at temperatures well above 100C.
PTFE material exhibits very high diffuse reflectance over the 250 - 2500 nm spectral range with reflectance greater than 99% between 400 nm and 1500 nm. Although PTFE’s temperature stability is suitable for laser applications, its high reflectance property is best suited for low level light applications. Another distinct advantage of the PTFE spheres is reliability: The material does not deteriorate with age and can be cleaned without destroying the mechanical integrity of the material.
A PTFE integrating sphere is immediately recognizable through a sphere port by the 7 mm thickness of the reflective material along the inside sphere wall. A PTFE GPS is constructed of two machined hemispheres, fitted together to form the interior sphere cavity and held together by an aluminum outer shell. A PTFE sphere is more expensive than a barium sulfate GPS due to the required machining and assembly. Since the walls have thickness, the size options for the PTFE spheres are different as well. Due to its high reflectivity and diffusivity, the optical throughput of a PTFE GPS is high, and hence more care is required when selecting port attachments and fixtures.